Recently I am researching about PRIMARY ALCOHOL OXIDATION; VISIBLE-LIGHT; ORGANIC FRAMEWORKS; RADICAL CATIONS; CARBON-CARBON; DEPOLYMERIZATION; HYDROGENOLYSIS; TRANSFORMATION; DEGRADATION; BIOMASS, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21975102, 21871107, 21774042, 21422401]. Published in ELSEVIER in AMSTERDAM ,Authors: Wang, YL; Liu, Y; He, JH; Zhang, YT. The CAS is 151-10-0. Through research, I have a further understanding and discovery of 1,3-Dimethoxybenzene. Application In Synthesis of 1,3-Dimethoxybenzene
It remains challenging to achieve the selective cleavage of C-C bonds in lignin or lignin model compounds to produce aromatic products in high yield and selectivity. We have developed a redox-neutral photocatalytic strategy to accomplish this goal in both beta-O-4 and beta-1 lignin models at room temperature (RT) via proton-coupled electron transfer (PCET) process without any pretreatments of substrate, by adjusting the alkalinity of base to obtain a lignin models/base PCET pair with a bond dissociation free energy close to 102 kcal/mol. Without breaking down C-beta-C-gamma bond and any C-O bonds, this PCET method is 100% atom economy and produces exclusive C-alpha-C-beta bond cleavage products, such as benzaldehydes (up to 97%) and phenyl ethers (up to 96%), in high to excellent yields and selectivities. Preliminary studies indicated that the PCET strategy is also effective for the depolymerization of native lignin at RT, thus providing significantly important foundation to the depolymerization of lignin. (C) 2019 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com