Application In Synthesis of 3-Methylbenzoic acid. Wang, ZH; Wang, XN; Wen, D; Long, XL in [Wang, Zhi-hao; Wang, Xin-ning; Wen, Di; Long, Xiang-li] East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai, Peoples R China published Isophthalic acid production catalyzed by Co(II) together with phosphotungstic acid loaded on carbon modified with tartaric acid in 2020.0, Cited 34.0. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7.
Background Isophthalic acid (IPA) is commercially produced using the Co-Mn-Br catalyst system, which suffers from the shortcomings of the discharge of CH3Br and corrosion of equipment. It is necessary to develop a technology to avoid the pollution caused by bromide. The production of IPA from the oxidation ofm-xylene (MX) by air is realized under catalysis with H3PW12O40(HPW) loaded on carbon and cobalt. Results Tartaric acid has been used to improve the catalytic activity of the HPW@C catalyst. Experiments indicate that the best modification condition is calcining the carbon at 450 degrees C for 4 h after being soaked in a 2.0 mol L(-1)tartaric acid solution for 10 h. Surface characterization reveals that the tartaric acid modification leads to an increase in the acid groups and a reduction in the basic groups on the carbon surface. Conclusions The MX conversion obtained using the HPW@C catalyst prepared from modified carbon is 6.77% over that obtained using the HPW@C catalyst prepared from the original carbon. The IPA generated using the former is 71.1% over that generated using the latter. The catalytic activity of the HPW@C catalyst relies on its surface chemical characteristics and physical properties. The surface chemistry plays a more important role than the physical properties. (c) 2020 Society of Chemical Industry
Application In Synthesis of 3-Methylbenzoic acid. Welcome to talk about 99-04-7, If you have any questions, you can contact Wang, ZH; Wang, XN; Wen, D; Long, XL or send Email.
Reference:
Isothiazole – Wikipedia,
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