An article Palladium-Catalyzed C-N Bond Cleavage of 2H-Azirines for the Synthesis of Functionalized alpha-Amido Ketones WOS:000459367100052 published article about RING-OPENING REACTION; STEREOSELECTIVE-SYNTHESIS; NEBER REARRANGEMENT; TERMINAL ALKYNES; CYCLOADDITION; CYCLIZATION; AZIRINES; ACIDS; OXAZOLES; ACCESS in [Xu, Fen; Si, Xiao-Ju; Song, Yuan-Yuan; Wang, Xing-Dong; Liu, Chun-Sen; Geng, Peng-Fei; Du, Miao] Zhengzhou Univ Light Ind, Coll Mat & Chem Engn, Zhengzhou 450002, Henan, Peoples R China in 2019.0, Cited 60.0. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7. Recommanded Product: 99-04-7
A Pd-catalyzed ring-opening reaction of 2H-azirines with carboxylic acids was developed. This reaction undergoes nucleophilic addition between 2,3-diaryl-2H-azirines and carboxylic acids followed by C-N single-bond cleavage and a subsequent thermal rearrangement. This method enables the rapid construction of valuable alpha-amido ketone derivatives with high atomic efficiency and superb functional group tolerance.
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Reference:
Isothiazole – Wikipedia,
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