Product Details of 93-97-0. Recently I am researching about ALKYL-N-NITROSOAMIDES; UND DIAZO-ESTER; NITROUS-ACID; ALCOHOLS; REARRANGEMENT; METHYLATION; SELECTIVITY; CHEMISTRY; MECHANISM; EXAMPLE, Saw an article supported by the JSPSMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of Science [24241023]; Yamaguchi University. Published in ELSEVIER SCI LTD in OXFORD ,Authors: Kamimura, A; Ikeda, K; Akinari, Y; Matsumoto, H; Kaiso, K. The CAS is 93-97-0. Through research, I have a further understanding and discovery of Benzoic anhydride
Stereochemistry of direct conversion of polyamides to hydroxyesters was investigated using model compounds. Optically active secondary-alkyl amines underwent the conversion to corresponding secondary alcohols in moderate yields by treatment with supercritical methanol in the presence of glycolic acid. The reaction progressed through almost completely stereochemical inversion to give secondary alcohols in high yields. Thus, the substitution reaction of the amino group to hydroxyl group progresses through S(N)2 type transition state accompanying with stereoinversion. (C) 2018 Published by Elsevier Ltd.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com