I found the field of Science & Technology – Other Topics very interesting. Saw the article Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes published in 2019. Quality Control of 1,3-Dimethoxybenzene, Reprint Addresses Konig, B (corresponding author), Univ Regensburg, Fak Chem & Pharm, D-93040 Regensburg, Germany.; Antonietti, M (corresponding author), Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, Res Campus Golm, D-14424 Potsdam, Germany.. The CAS is 151-10-0. Through research, I have a further understanding and discovery of 1,3-Dimethoxybenzene
Photoexcited electron-hole pairs on a semiconductor surface can engage in redox reactions with two different substrates. Similar to conventional electrosynthesis, the primary redox intermediates afford only separate oxidized and reduced products or, more rarely, combine to one addition product. Here, we report that a stable organic semiconductor material, mesoporous graphitic carbon nitride (mpg-CN), can act as a visible-light photoredox catalyst to orchestrate oxidative and reductive interfacial electron transfers to two different substrates in a two-or three-component system for direct twofold carbon-hydrogen functionalization of arenes and heteroarenes. The mpg-CN catalyst tolerates reactive radicals and strong nucleophiles, is straightforwardly recoverable by simple centrifugation of reaction mixtures, and is reusable for at least four catalytic transformations with conserved activity.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com