An article Enantioselective 1,2-Addition of alpha-Aminoalkyl Radical to Aldehydes via Visible-Light Photoredox Initiated Chiral Oxazaborolidinium Ion Catalysis WOS:000574920200030 published article about SYNERGISTIC CATALYSIS; CONJUGATE ADDITION; ELECTRON-TRANSFER; LEWIS-ACID; ALCOHOLS; KETONES; PHOTOCATALYSIS; EQUIVALENTS; DERIVATIVES; ACTIVATION in [Kim, Jae Yeon; Lee, Yea Suel; Choi, Yuna; Ryu, Do Hyun] Sungkyunkwan Univ, Dept Chem, Suwon 16419, South Korea in 2020, Cited 77. The Name is Benzoic anhydride. Through research, I have a further understanding and discovery of 93-97-0. Recommanded Product: 93-97-0
Enantioselective 1,2-addition reaction of alpha-aminoalkyl radical to alpha,beta-unsaturated or aromatic aldehydes to synthesize highly optically active beta-amino alcohols has been developed. In the presence of chiral oxazaborolidinium ion catalyst and photosensitizer, the reaction provides desired beta-amino allylic or benzylic alcohols with high yields (up to 99%) and high enantioselectivities (up to 98% ee).
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Reference:
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