SDS of cas: 99-04-7. Recently I am researching about C-H BONDS; CARBON-DIOXIDE; ELECTROCHEMICAL CONVERSION; ORGANOZINC REAGENTS; ARYLSULFONIUM SALTS; ELECTRON-DONORS; ARYL HALIDES; CHLORIDES; CARBOZINCATION; TRANSFORMATION, Saw an article supported by the JSPS KAKENHI GrantMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [JP18K14212, JP16H04109, JP18H04254, JP18H04409, JP19H00895]; JSPSMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of Science; JST CREST Grant, Japan [JPMJCR19R4]; ICIQ FEDER/MICIU [AEI/PGC2018-096839-B-100]; la Caixa FoundationLa Caixa Foundation [100010434, LCF/B10, 1 SO15/52260010]; la CaixaLa Caixa Foundation. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Yanagi, T; Somerville, RJ; Nogi, K; Martin, R; Yorimitsu, H. The CAS is 99-04-7. Through research, I have a further understanding and discovery of 3-Methylbenzoic acid
Nickel-catalyzed reductive carboxylation reactions of aryl electrophiles typically require the use of metallic reducing agents. At present, the prevailing perception is that these serve as both a source of electrons and as a source of Lewis acids that may aid CO2 insertion into the Ni-C bond. Herein, we provide evidence for the in situ formation of organometallic species from the metallic reductant, a step that has either been ruled out or has been unexplored in catalytic carboxylation reactions with metal powder reductants. Specifically, we demonstrate that Zn(O) acts as a reductant and that Zn(II) generates arylzinc species that might play a role in the C(sp(2))-S carboxylation of arylsulfonium salts. Overall, the reductive Ni-catalyzed C(sp(2))-S carboxylation reaction proceeds under mild conditions in a non-amide solvent, displays a wide substrate scope, and can be applied to the formal para C-H carboxylation of arenes.
SDS of cas: 99-04-7. Bye, fridends, I hope you can learn more about C8H8O2, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com