Kudo, H; Naritomi, K; Onishi, S; Maekawa, H; Mondarte, EAQ; Suthiwanich, K; Hayashi, T in [Kudo, Hiroto; Naritomi, Kazunori; Onishi, Shuto; Maekawa, Hiroyuki] Kansai Univ, Fac Chem Mat & Bioengn, Dept Chem & Mat Engn, Suita, Osaka 5648680, Japan; [Mondarte, Evan A. Q.; Suthiwanich, Kasinan] Tokyo Inst Technol, Dept Mat Sci & Engn, Midori Ku, Yokohama, Kanagawa 2268502, Japan; [Hayashi, Tomohiro] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Elect Chem, Kawaguchi, Saitama 3320012, Japan published Living Ring-Expansion Polymerization of Thiirane with Cyclic Monocarbamothioates in 2020, Cited 37. Formula: C8H10O2. The Name is 1,3-Dimethoxybenzene. Through research, I have a further understanding and discovery of 151-10-0.
We synthesized two kinds of monocarbamothioates TZO(R) containing a thiazolidin-2-one (TZO) skeleton and TZD(R) containing a thiazolidine-2,4-dione (TZD) skeleton. In the reaction of TZO(R) and phenoxypropyrenesulfide (PPS) using tetrabutylammonium chloride (TBAC) as a catalyst in 1-methyl-2-pyrrolidinone at 60 degrees C, anionic ring-opening polymerization of PPS proceeded to give the corresponding linear polysulfides, polyPPS, with M-n = 75 860-206 700 (M-w/M-n = 1.54-1.73) in high yield. In contrast, in the reaction of TZD(R) and PPS, the continuous insertion reaction of PPS into TZD(R), i.e., living ring-expansion polymerization, occurred to afford cyclic polysulfides TZD(R)-c-poly(PPS)(n) with M-n = 1870-33 420 (M-w/M-n = 1.07-1.26) in high yield. The ring size could be controlled by the feed ratio of TZD(R)/PPS in the range of 1/5-1/100.
Formula: C8H10O2. Welcome to talk about 151-10-0, If you have any questions, you can contact Kudo, H; Naritomi, K; Onishi, S; Maekawa, H; Mondarte, EAQ; Suthiwanich, K; Hayashi, T or send Email.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com