Recommanded Product: 3-Methylbenzoic acid. Recently I am researching about N-HETEROCYCLIC CARBENE; HIGH-THROUGHPUT EXPERIMENTATION; ELECTRON-TRANSFER PROPERTIES; COOPERATIVE CATALYSIS; ACTIVE ALDEHYDES; REDOX BEHAVIOR; OXIDATION; ALKYLATION; ACYL; ACYLATION, Saw an article supported by the NIGMS NIH HHSUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USANIH National Institute of General Medical Sciences (NIGMS) [R01 GM073072, R01 GM131431] Funding Source: Medline. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Bay, AV; Fitzpatrick, KP; Betori, RC; Scheidt, KA. The CAS is 99-04-7. Through research, I have a further understanding and discovery of 3-Methylbenzoic acid
As a key element in the construction of complex organic scaffolds, the formation of C-C bonds remains a challenge in the field of synthetic organic chemistry. Recent advancements in single-electron chemistry have enabled new methods for the formation of various C-C bonds. Disclosed herein is the development of a novel single-electron reduction of acyl azoliums for the formation of ketones from carboxylic acids. Facile construction of the acyl azolium in situ followed by a radical-radical coupling was made possible merging N-heterocyclic carbene (NHC) and photoredox catalysis. The utility of this protocol in synthesis was showcased in the late-stage functionalization of a variety of pharmaceutical compounds. Preliminary investigations using chiral NHCs demonstrate that enantioselectivity can be achieved, showcasing the advantages of this protocol over alternative methodologies.
Welcome to talk about 99-04-7, If you have any questions, you can contact Bay, AV; Fitzpatrick, KP; Betori, RC; Scheidt, KA or send Email.. Recommanded Product: 3-Methylbenzoic acid
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com