Product Details of 93-97-0. Recently I am researching about AEROBIC DEHYDROGENATION; CYCLIC ENONES; PALLADIUM; ALPHA,BETA-DEHYDROGENATION; ESTERS, Saw an article supported by the Yale University; Sloan FoundationAlfred P. Sloan Foundation; Nalas Engineering; AmgenAmgen; NSF (CAREER)National Science Foundation (NSF)NSF – Office of the Director (OD) [1653793]; NIHUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USA [T32GM067543]; NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCESUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USANIH National Institute of General Medical Sciences (NIGMS) [T32GM067543] Funding Source: NIH RePORTER. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Huang, D; Szewczyk, SM; Zhang, PP; Newhouse, TR. The CAS is 93-97-0. Through research, I have a further understanding and discovery of Benzoic anhydride
We herein disclose the first report of a first-row transition metal-catalyzed alpha,beta-dehydrogenation of carbonyl compounds using allyl-nickel catalysis. This development overcomes several limitations of previously reported allyl-palladium-catalyzed oxidation, and is further leveraged for the development of an oxidative cycloalkenylation reaction that provides access to bicycloalkenones with fused, bridged, and spirocyclic ring systems using unactivated ketone and alkene precursors.
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Reference:
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