Recently I am researching about SODIUM, Saw an article supported by the German Academic Scholarship Foundation; DFGGerman Research Foundation (DFG)European Commission; LMU; Projekt DEAL. Category: isothiazole. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Harenberg, JH; Weidmann, N; Wiegand, AJ; Hoefer, CA; Annapureddy, RR; Knochel, P. The CAS is 151-10-0. Through research, I have a further understanding and discovery of 1,3-Dimethoxybenzene
We report the on-demand generation of hexane-soluble (2-ethylhexyl)sodium (1) from 3-(chloromethyl)heptane (2) using a sodium-packed-bed reactor under continuous flow conditions. Thus, the resulting solution of 1 is free of elemental sodium and therefore suited for a range of synthetic applications. This new procedure avoids the storage of an alkylsodium and limits the handling of metallic sodium to a minimum. (2-Ethylhexyl)sodium (1) proved to be a very useful reagent and undergoes in-line Br/Na-exchanges as well as directed sodiations. The resulting arylsodium intermediates are subsequently trapped in batch with various electrophiles such as ketones, aldehydes, Weinreb-amides, imines, allyl bromides, disulfides and alkyl iodides. A reaction scale-up of the Br/Na-exchange using an in-line electrophile quench was also reported.
Welcome to talk about 151-10-0, If you have any questions, you can contact Harenberg, JH; Weidmann, N; Wiegand, AJ; Hoefer, CA; Annapureddy, RR; Knochel, P or send Email.. Category: isothiazole
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com