Han, JL; Qin, Y; Ju, CW; Zhao, DB in [Han, Jie-Lian; Qin, Ying; Ju, Cheng-Wei; Zhao, Dongbing] Nankai Univ, Coll Chem, State Key Lab, 94 Weijin Rd, Tianjin 300071, Peoples R China; [Han, Jie-Lian; Qin, Ying; Ju, Cheng-Wei; Zhao, Dongbing] Nankai Univ, Coll Chem, Inst Elementoorgan Chem, 94 Weijin Rd, Tianjin 300071, Peoples R China published Divergent Synthesis of Vinyl-, Benzyl-, and Borylsilanes: Aryl to Alkyl 1,5-Palladium Migration/Coupling Sequences in 2020, Cited 91. Category: isothiazole. The Name is Benzoic anhydride. Through research, I have a further understanding and discovery of 93-97-0.
Organosilicon compounds have been extensively utilized both in industry and academia. Studies on the syntheses of diverse organosilanes is highly appealing. Through-space metal/hydrogen shifts allow functionalization of C-H bonds at a remote site, which are otherwise difficult to achieve. However, until now, an aryl to alkyl 1,5-palladium migration process seems to have not been presented. Reported herein is the remote olefination, arylation, and borylation of a methyl group on silicon to access diverse vinyl-, benzyl-, and borylsilanes, constituting a unique C(sp(3))-H transformation based on a 1,5-palladium migration process.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com