In 2019.0 J ORG CHEM published article about ALKYLATION; INHIBITORS; BONDS; AMIDES; FUNCTIONALIZATION; C(SP(2))-H; DISCOVERY; ARYLATION; PEROXIDE; REAGENTS in [Lv, Weiwei; Wen, Si; Liu, Jing; Cheng, Guolin] Huaqiao Univ, Coll Mat Sci & Engn, Xiamen 361021, Fujian, Peoples R China in 2019.0, Cited 46.0. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7. COA of Formula: C8H8O2
A palladium-catalyzed methylation of C-H bonds of benzoic acids with di-tert-butyl peroxide as the methylating reagent under an external oxidant and ligand-free conditions has been achieved. The reaction is found to be directed by a weakly coordinating carboxyl group, offering a facile route for the synthesis of highly functionalized ortho-methyl benzoic acids.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com