An article Ring-Opening Ortho-C-H Allylation of Benzoic Acids with Vinylcyclopropanes: Merging Catalytic C-H and C-C Activation Concepts WOS:000485089300038 published article about CARBOXYLIC-ACIDS; BOND FUNCTIONALIZATION; HYDROARYLATION; ARYLATION; ALKYNES; CYCLOPROPENES; ROUTES; ARENES; SP(2) in [Hu, Zhiyong; Hu, Xiao-Qiang; Zhang, Guodong; Goossben, Lukas J.] Ruhr Univ Bochum, Lehrstuhl Organ Chem 1, Univ Str 150, D-44801 Bochum, Germany in 2019, Cited 65. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7. SDS of cas: 99-04-7
A Ru-catalyzed selective and atom-economic ortho-C-H allylation of aromatic acids with vinylcyclopropanes is reported. The reaction proceeds with selective cleavage of both a C-H and a C-C bond. A wide range of allylarenes were synthesized in high yields and stereoselectivities. The vinylcyclopropane substrates can optionally be generated in situ from a diazo compound and 1,3-butadiene. Concise syntheses of isocoumarin and 3,4-dihydroisocoumarin derivatives underline the synthetic utility of the reaction.
SDS of cas: 99-04-7. Welcome to talk about 99-04-7, If you have any questions, you can contact Hu, ZY; Hu, XQ; Zhang, GD; Goossben, LJ or send Email.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com