de Oliveira, IM; Esteves, CHA; Darbem, MP; Pimenta, DC; Zukerman-Schpector, J; Ferreira, AG; Stefani, HA; Manarin, F in [de Oliveira, Isadora M.] Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, Sao Paulo, SP, Brazil; [Esteves, C. Henrique A.; Darbem, Mariana P.; Stefani, Helio A.] Univ Sao Paulo, Fac Ciencias Farmaceut, Dept Farm, Sao Paulo, SP, Brazil; [Pimenta, Daniel C.] Inst Butantan, Sao Paulo, SP, Brazil; [Zukerman-Schpector, Julio; Ferreira, Antonio G.] Univ Fed Sao Carlos, Dept Quim, Sao Carlos, SP, Brazil; [Manarin, Flavia] Univ Estadual Oeste Parana, CECE, Toledo, PR, Brazil published Iron (III)-Promoted Synthesis of Substituted 4H-Chalcogenochromenes and Chemoselective Functionalization in 2019.0, Cited 36.0. COA of Formula: C9H10O3. The Name is 2,5-Dimethoxybenzaldehyde. Through research, I have a further understanding and discovery of 93-02-7.
The iron(III)-promoted synthesis of densely-substituted 4H-chalcogenchromene from organochalcogen propargylamines in the presence of diaryl dichalcogenides is reported. Subsequent C2-functionalization with electrophiles and potassium trifluoroborate salts via Suzuki-Miyaura coupling reaction are also presented. A plausible mechanism based on HRMS experiments is proposed and discussed.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com