An article Highly Selective and Divergent Acyl and Aryl Cross-Couplings of Amides via Ir-Catalyzed C-H Borylation/N-C(O) Activation WOS:000562077400058 published article about MEDICINAL CHEMISTS TOOLBOX; SUZUKI-MIYAURA; KETONE SYNTHESIS; CLEAVAGE; ARENES; FUNCTIONALIZATION; ESTERS in [Gao, Pengcheng; Szostak, Michal] Rutgers State Univ, Dept Chem, Newark, NJ 07102 USA in 2020, Cited 56. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7. Recommanded Product: 99-04-7
Herein, we demonstrate that amides can be readily coupled with nonactivated arenes via sequential Ir-catalyzed C-H borylation/N-C(O) activation. This methodology provides facile access to biaryl ketones and biaryls by the sterically controlled Ir-catalyzed C-H borylation and divergent acyl and decarbonylative amide N-C(O) and C-C activation. The methodology diverts the traditional acylation and arylation regioselectivity, allowing us to directly utilize readily available arenes and amides to produce valuable ketone and biaryl motifs.
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