Daley, RA; Topczewski, JJ in [Daley, Ryan A.; Topczewski, Joseph J.] Univ Minnesota, Dept Chem, Minneapolis, MN 44544 USA published Palladium-catalyzed salt-free double decarboxylative aryl allylation in 2019, Cited 26. Category: isothiazole. The Name is 2,6-Difluorobenzoic acid. Through research, I have a further understanding and discovery of 385-00-2.
This report describes a palladium-catalyzed decarboxylative aryl allylation between unactivated benzoic acids and allylic carbonates. This transformation successfully couples a variety of carbonates and benzoic acids in good yield (up to 94%) using 1 mol% palladium. This salt free allyl-arylation proceeds without added base, copper, or silver. The only stoichiometric byproducts are carbon dioxide and tert-butanol.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com