An article Construction of Axial Chirality and Silicon-Stereogenic Center via Rh-Catalyzed Asymmetric Ring-Opening of Silafluorenes WOS:000641296000067 published article about ENANTIOSELECTIVE SYNTHESIS; SILANES; DESYMMETRIZATION; HYDROSILYLATION; DIBENZOSILOLES; ANHYDRIDES; ACTIVATION; ACYLATION; BIARYLS; CARBON in [Bi, Xiufen; Feng, Jia; Xue, Xiaoping; Gu, Zhenhua] Univ Sci & Technol China, Ctr Excellence Mol Synth, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China; [Bi, Xiufen; Feng, Jia; Xue, Xiaoping; Gu, Zhenhua] Univ Sci & Technol China, Ctr Excellence Mol Synth, Dept Chem, Hefei 230026, Anhui, Peoples R China; [Gu, Zhenhua] Minjiang Univ, Ocean Coll, Fuzhou 350108, Fujian, Peoples R China in 2021, Cited 67. Quality Control of Benzoic anhydride. The Name is Benzoic anhydride. Through research, I have a further understanding and discovery of 93-97-0
A rhodium-catalyzed enantioselective ring-opening/acylation of silafluorenes is reported. The newly developed bulky phosphoramidite ligand, in combination with methanol as the additive, enabled the reaction to create one axial chirality and one silicon-stereogenic center in a highly selective manner by only cleavage of one Si-C bond.
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Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com