An article Ni-Catalyzed Carboxylation of C(sp(2))-S Bonds with CO2: Evidence for the Multifaceted Role of Zn WOS:000513099200047 published article about C-H BONDS; CARBON-DIOXIDE; ELECTROCHEMICAL CONVERSION; ORGANOZINC REAGENTS; ARYLSULFONIUM SALTS; ELECTRON-DONORS; ARYL HALIDES; CHLORIDES; CARBOZINCATION; TRANSFORMATION in [Somerville, Rosie J.; Martin, Ruben] Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain; [Martin, Ruben] ICREA, Barcelona 08010, Spain; [Yanagi, Tomoyuki; Nogi, Keisuke; Yorimitsu, Hideki] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan; [Somerville, Rosie J.] Univ Rovira & Virgili, Dept Quim Analit & Quim Organ, E-43007 Tarragona, Spain in 2020.0, Cited 79.0. Quality Control of 3-Methylbenzoic acid. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7
Nickel-catalyzed reductive carboxylation reactions of aryl electrophiles typically require the use of metallic reducing agents. At present, the prevailing perception is that these serve as both a source of electrons and as a source of Lewis acids that may aid CO2 insertion into the Ni-C bond. Herein, we provide evidence for the in situ formation of organometallic species from the metallic reductant, a step that has either been ruled out or has been unexplored in catalytic carboxylation reactions with metal powder reductants. Specifically, we demonstrate that Zn(O) acts as a reductant and that Zn(II) generates arylzinc species that might play a role in the C(sp(2))-S carboxylation of arylsulfonium salts. Overall, the reductive Ni-catalyzed C(sp(2))-S carboxylation reaction proceeds under mild conditions in a non-amide solvent, displays a wide substrate scope, and can be applied to the formal para C-H carboxylation of arenes.
Quality Control of 3-Methylbenzoic acid. About 3-Methylbenzoic acid, If you have any questions, you can contact Yanagi, T; Somerville, RJ; Nogi, K; Martin, R; Yorimitsu, H or concate me.
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