Recently I am researching about AEROBIC OXIDATION; SELECTIVE OXIDATION; RUTHENIUM CATALYST; WATER; METAL; COMPLEXES; ALDEHYDES; SALTS; CONVERSION; AMIDATION, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21502062]; Scientific Research Program Guiding Project of Hubei Provincial Department of Education [B2019135]; Teacher’s Scientific Research Ability Cultivation Fund, Hubei University of Arts and Science (Natural Science) [2018kypy001]; Open Foundation of Discipline of Hubei University of Arts and Science [XK2019038]; Tomsk Polytechnic University Competitiveness Enhancement Program [VIU69-2019]. Safety of 3-Methylbenzoic acid. Published in MDPI in BASEL ,Authors: Wang, WQ; Cheng, H; Yuan, Y; He, YQ; Wang, HJ; Wang, ZQ; Sang, W; Chen, C; Verpoort, F. The CAS is 99-04-7. Through research, I have a further understanding and discovery of 3-Methylbenzoic acid
The transition-metal-catalyzed alcohol dehydrogenation to carboxylic acids has been identified as an atom-economical and attractive process. Among various catalytic systems, Ru-based systems have been the most accessed and investigated ones. With our growing interest in the discovery of new Ru catalysts comprising N-heterocyclic carbene (NHC) ligands for the dehydrogenative reactions of alcohols, we designed and prepared five NHC/Ru complexes ([Ru]-1-[Ru]-5) bearing different ancillary NHC ligands. Moreover, the effects of ancillary and additional ligands on the alcohol dehydrogenation with KOH were thoroughly explored, followed by the screening of other parameters. Accordingly, a highly active catalytic system, which is composed of [Ru]-5 combined with an additional NHC precursor L5, was discovered, affording a variety of acid products in a highly efficient manner. Gratifyingly, an extremely low Ru loading (125 ppm) and the maximum TOF value until now (4800) were obtained.
Safety of 3-Methylbenzoic acid. About 3-Methylbenzoic acid, If you have any questions, you can contact Wang, WQ; Cheng, H; Yuan, Y; He, YQ; Wang, HJ; Wang, ZQ; Sang, W; Chen, C; Verpoort, F or concate me.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com