Application In Synthesis of Benzoic anhydride. Authors Kim, W; Koo, J; Lee, HG in ROYAL SOC CHEMISTRY published article about in [Kim, Weonjeong; Koo, Jangwoo; Lee, Hong Geun] Seoul Natl Univ, Coll Nat Sci, Dept Chem, 1 Gwanak Ro, Seoul 08826, South Korea in 2021, Cited 77. The Name is Benzoic anhydride. Through research, I have a further understanding and discovery of 93-97-0
A mechanistically unique functionalization strategy for a benzylic C(sp(3))-H bond has been developed based on the facile oxidation event of indole substrates. This novel pathway was initiated by efficient radical generation at the benzylic position of the substrate, with subsequent transition metal catalysis to complete the overall transformation. Ultimately, an aryl or an acyl group could be effectively delivered from an aryl (pseudo)halide or an acid anhydride coupling partner, respectively. The developed method utilizes mild conditions and exhibits a wide substrate scope for both substituted indoles and C(sp(2))-based reaction counterparts. Mechanistic studies have shown that competitive hydrogen atom transfer (HAT) processes, which are frequently encountered in conventional methods, are not involved in the product formation process of the developed strategy.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com