Han, J; Zhou, W; Zhang, PC; Wang, HM; Zhang, RH; Wu, HH; Zhang, JL in [Han, Jie; Zhou, Wei; Zhang, Pei-Chao; Wang, Huamin; Zhang, Ronghua; Wu, Hai-Hong; Zhang, Junliang] East China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Sch Chem & Mol Engn, 3663 N Zhongshan Rd, Shanghai 200062, Peoples R China; [Zhang, Junliang] Fudan Univ, Dept Chem, 2005 Songhu Rd, Shanghai 200438, Peoples R China published Design and Synthesis of WJ-Phos, and Application in Cu-Catalyzed Enantioselective Boroacylation of 1,1-Disubstituted Allenes in 2019, Cited 78. SDS of cas: 99-04-7. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7.
The highly enantioselective copper-catalyzed three-component boroacylation of 1,1-disubstituted allenes is reported by using a class of chiral ligands (WJ-Phos), delivering various functionalized organoboron compounds bearing an all-carbon stereocenter in moderate to good yields with high enantioselectivities. WJ-Phos is a ferrocene-derived chiral sulfinamide phosphine ligand and can be easily synthesized in gram-scale from readily available starting materials in short steps. The salient features of this reaction include moderate to good yields, high enantioselectivities, gram-scale synthesis, diverse synthetic transformations, and the development of a new chiral ligand.
SDS of cas: 99-04-7. About 3-Methylbenzoic acid, If you have any questions, you can contact Han, J; Zhou, W; Zhang, PC; Wang, HM; Zhang, RH; Wu, HH; Zhang, JL or concate me.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com