Recently I am researching about HIGH-DILUTION SYNTHESIS; SUPPORTED SYNTHESIS; SINGLE; POLYMERIZATION; CONDENSATION; GRAPHITE; DRIVEN; 2D, Saw an article supported by the Natural Sciences and Engineering Research Council of Canada (NSERC)Natural Sciences and Engineering Research Council of Canada (NSERC); Centre quebecois sur les materiaux fonctionnels/Quebec Centre for Advanced Materials (CQMF/QCAM); Czech Science foundationGrant Agency of the Czech Republic [18-20357S]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21902063]; Ministry of Education, Youth and Sports of the Czech RepublicMinistry of Education, Youth & Sports – Czech Republic [LM2015073]; project ProNanoEnviCz – Ministry of Education, Youth, and Sports of the Czech Republic [CZ.02.1.01/0.0/0.0/16_013/0001821]; European Union -European Structural and Investments; Nouvelle Aquitaine region. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Fu, CY; Miksatko, J; Assies, L; Vrkoslav, V; Orlandi, S; Kalbac, M; Kovaricek, P; Zeng, XB; Zhou, BP; Muccioli, L; Perepichka, DF; Orgiu, E. The CAS is 151-10-0. Through research, I have a further understanding and discovery of 1,3-Dimethoxybenzene. Safety of 1,3-Dimethoxybenzene
Surface-confined synthesis is a promising approach to build complex molecular nanostructures including macrocycles. However, despite the recent advances in on-surface macro- cyclization under ultrahigh vacuum, selective synthesis of monodisperse and multicomponent macrocycles remains a challenge. Here, we report on an on-surface formation of [6 + 6] Schiff-base macrocycles via dynamic covalent chemistry. The macrocycles form two-dimensional crystalline domains on the micrometer scale, enabled by dynamic conversion of open-chain oligomers into well-defined similar to 3.0 nm hexagonal macrocycles. We further show that by tailoring the length of the alkyl substituents, it is possible to control which of three possible products-oligomers, macrocycles, or polymers-will form at the surface. In situ scanning tunneling microscopy imaging combined with density functional theory calculations and molecular dynamics simulations unravel the synergistic effect of surface confinement and solvent in leading to preferential on-surface macrocyclization.
Safety of 1,3-Dimethoxybenzene. About 1,3-Dimethoxybenzene, If you have any questions, you can contact Fu, CY; Miksatko, J; Assies, L; Vrkoslav, V; Orlandi, S; Kalbac, M; Kovaricek, P; Zeng, XB; Zhou, BP; Muccioli, L; Perepichka, DF; Orgiu, E or concate me.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com