An article Visible-Light-Induced Deoxygenation/Defluorination Protocol for Synthesis of gamma,gamma-Difluoroallylic Ketones WOS:000508468200076 published article about F BOND ACTIVATION; C-F; GEM-DIFLUOROALKENES; FLUORINE ELIMINATION; BIOLOGICAL-ACTIVITY; AMINO-ACIDS; DESIGN; TRIFLUOROMETHYLATION; DERIVATIVES; CYCLIZATION in [Guo, Yuan-Qiang; Wang, Ruiguo; Song, Hongjian; Liu, Yuxiu; Wang, Qingmin] Nankai Univ, Coll Chem, Res Inst Elementoorgan Chem, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China; [Wang, Qingmin] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China in 2020.0, Cited 54.0. Recommanded Product: 99-04-7. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7
Herein, we describe an efficient, practical photocatalytic deoxygenation/defluorination protocol for the synthesis of gamma,gamma-difluoroallylic ketones from commercially available aromatic carboxylic acids, triphenylphosphine, and alpha-trifluoromethyl alkenes. The protocol has good functional group tolerance and a broad substrate scope. Using this method, we accomplished the late-stage functionalization of several bioactive molecules.
Recommanded Product: 99-04-7. About 3-Methylbenzoic acid, If you have any questions, you can contact Guo, YQ; Wang, RG; Song, HJ; Liu, YX; Wang, QM or concate me.
Reference:
Isothiazole – Wikipedia,
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