Recently I am researching about CROSS-COUPLING REACTIONS; HIGHLY-ACTIVE CATALYST; EFFICIENT SYNTHESIS; PHOSPHINE; TRANSMETALATION; COMPLEXES; AMINATION; SCOPE, Saw an article supported by the VinnovaVinnova [INNOV 2015/29]; [2016-02110]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Byrne, L; Skold, C; Norrby, PO; Munday, RH; Turner, AR; Smith, PD. The CAS is 151-10-0. Through research, I have a further understanding and discovery of 1,3-Dimethoxybenzene. SDS of cas: 151-10-0
Here we describe the development of biaryl 2,5-diphenylphospholanes as a new class of C-2-symmetric, monodentate ligands for asymmetric Suzuki-Miyaura (ASM) reactions. Screening of a series of exemplary phospholanes led to the identification of two ligands that were used to prepare a range of atropisomeric biaryl and heterobiaryl products with good to excellent levels of enantioselectivity (up to 97:3 e.r.) under mild conditions. DFT studies suggest that the formation of a constraining ligand pocket and coordination of one of the biaryl methoxy groups in the optimised ligands to the metal centre is crucial for restricting conformational freedom in the bond-forming step.
SDS of cas: 151-10-0. About 1,3-Dimethoxybenzene, If you have any questions, you can contact Byrne, L; Skold, C; Norrby, PO; Munday, RH; Turner, AR; Smith, PD or concate me.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com