Recently I am researching about RING-CLOSING METATHESIS; BASE-PROMOTED REARRANGEMENT; CLAISEN REARRANGEMENT; POLYCYCLIC REARRANGEMENTS; ETHYL DIAZOACETATE; CHEMISTRY; SYSTEMS; SYN; CIS; (D3)-TRISHOMOCUBANE, Saw an article supported by the DRDO (Defence Research and Development Organization), New Delhi [ARDB/01/1041849/M/1]; DST (Department of Science and Technology)Department of Science & Technology (India) [SR/S2/JCB-33/2010]; University Grants Commission (UGC), New DelhiUniversity Grants Commission, India. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Kotha, S; Cheekatla, SR. The CAS is 93-02-7. Through research, I have a further understanding and discovery of 2,5-Dimethoxybenzaldehyde. Computed Properties of C9H10O3
The design and synthesis of highly decorated cage [4.3.2] propellanes and D-3-trishomocubanes have been reported via ring-closing metathesis (RCM), [4 + 2] cycloaddition and acid-catalyzed rearrangement as key steps. These cage polycycles were prepared starting with inexpensive synthons such as 2,5-dimethoxybenzaldehyde and endo-dicyclopentadiene. Propellanes containing fused spiro[4.4]nonane ring system was realized by RCM protocol. Interestingly, the dimethoxy cage propellane derivative was observed instead of the rearranged product with Lewis acid such as BF3 center dot MeOH. Several intricate cage structures were synthesized from rearrangement approach that are difficult to generate by conventional routes.
About 2,5-Dimethoxybenzaldehyde, If you have any questions, you can contact Kotha, S; Cheekatla, SR or concate me.. Computed Properties of C9H10O3
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com