Name: 2,6-Difluorobenzoic acid. Recently I am researching about AROMATIC AMIDES; CATALYZED ALKYLATION; BONDS; DERIVATIVES, Saw an article supported by the MEXTMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT) [17H06091]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Das, A; Chatani, N. The CAS is 385-00-2. Through research, I have a further understanding and discovery of 2,6-Difluorobenzoic acid
The Rh-catalyzed C-H alkylation of benzylamine derivatives with unactivated 1-alkenes that proceeds via a picolinamide directing group is reported. The crucial role of an acid additive in this transformation is confirmed. Aromatic acids showed high linear selectivity, and aliphatic acids provided branched alkylation products as the major product. The reaction has a broad scope for benzylamines and alkenes. Deuterium labeling experiments suggest that a Rh-carbene intermediate is involved in the case of linear product formation. A different reaction pathway, however, appears to be involved in the case of branched alkylation products, and this pathway also appeared to be a minor pathway in linear-selective reactions.
About 2,6-Difluorobenzoic acid, If you have any questions, you can contact Das, A; Chatani, N or concate me.. Name: 2,6-Difluorobenzoic acid
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com