Recommanded Product: 3-Methylbenzoic acid. Recently I am researching about CARBOXYLIC-ACIDS; BOND FUNCTIONALIZATIONS; OXIDASE CATALYSIS; ALKENYLATIONS; DEHYDROGENATION; ISOPESTACIN; STRATEGY; WATER, Saw an article supported by the Natural Science Foundation of Shandong Province, ChinaNatural Science Foundation of Shandong Province [ZR2016JL009]; University of Jinan. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Wang, R; Xu, HY; Li, TT; Zhang, Y; Wang, SF; Chen, GZ; Li, CC; Zhao, HQ. The CAS is 99-04-7. Through research, I have a further understanding and discovery of 3-Methylbenzoic acid
A catalytic annulation cascade is achieved that affords an efficient access to phthalides from readily available benzoic acids and saturated ketones. The reaction is catalyzed by a bimetallic Ir/Cu system and proceeds via the combination of Cu-catalyzed dehydrogenation of ketones and Ir-catalyzed direct C-H functionalization under the assistance of the weakly coordinating carboxyl followed by the beta-H elimination and intramolecular Michael addition. This method shows a broad scope of substrates and good functional group tolerance. The protocol furnishes an alternative strategy for the construction of diverse 3-substituted phthalides.
Recommanded Product: 3-Methylbenzoic acid. About 3-Methylbenzoic acid, If you have any questions, you can contact Wang, R; Xu, HY; Li, TT; Zhang, Y; Wang, SF; Chen, GZ; Li, CC; Zhao, HQ or concate me.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com