Safety of 2-(Naphthalen-2-yl)acetic acid, Academic researchers, R&D teams, teachers, students, policy makers and the media all rely on us to share knowledge that is reliable, accurate and cutting-edge. 581-96-4, Name is 2-(Naphthalen-2-yl)acetic acid, SMILES is O=C(O)CC1=CC=C2C=CC=CC2=C1, belongs to isothiazole compound. In a article, author is Clerici, F, introduce new discover of the category.
3-Diethylamino-4-(4-methoxyphenyl)-isothiazole 1,1-dioxide(1) was made to react with arylalkyl- and arylazides 2. Cycloadducts 3, which could he isolated in some cases, afforded N-arylalkyl or N-aryl-thiadiazabicyclo[3.1.0]hexene derivatives 4 through N-2-elimination. Thermal rearrangements of N-aryl- and N-beta-phenylethyl substituted compounds 4b-e, produced derivatives of 1,2-thiazete 1,1-dioxide 5, 1,2,6-thiadiazine 1,1-dioxide 6 and pyrazole 7. The reaction can be optimized to afford compounds 6 in synthetically useful yield. In the case of N-benzyl-thiadiazabicyclo[3.1.0]hexene derivative 4a the different substitution on the aziridine nitrogen produced a different reaction course, affording the thiadiazine derivative 6a and the pyrimidine derivative 8. Copyright (C) 1996 Elsevier Science Ltd
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com