New Advances in Chemical Research, April 2021. Computed Properties of https://www.ambeed.com/products/22884-95-3.html, While the job of a research scientist varies, most chemistry careers in research are based in laboratories, where research is conducted by teams following scientific methods and standards. 22884-95-3, Name is 3,4-Dimethylbenzonitrile, SMILES is CC1=C(C)C=C(C=C1)C#N, belongs to isothiazole compound. In a article, author is Li, Meng-Fan, introduce new discover of the category.
The combination of Pd(TFA)(2) and an N,N’-disulfonyl bisimidazoline ligand shows high catalytic activity and excellent asymmetric induction in the addition of arylboronic acids to cyclic N-sulfonyl ketimines including benzo[d]-isothiazole-1,1-dioxides, benzo[e][1,2,3]oxathiazine-2,2-dioxides, and 1,2,5-thiadiazole-1,1-dioxides, by which three types of chiral quaternary carbon-containing sultams with substantial substitution diversity were synthesized with high yields and excellent enantioselectivities (up to >99% ee). The current catalysis demonstrated a remarkable tolerance to oxygen and thus provided an operationally simple approach for constructing enantioenriched cyclic quaternary stereocenters.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com