New Advances in Chemical Research, April 2021. Related Products of 2144-08-3, In heterogeneous catalysis, catalysts provide a surface to which reactants bind in a process of adsorption. The reactant in an enzyme-catalyzed reaction is called a substrate. 2144-08-3, Name is 2,3,4-Trihydroxybenzaldehyde, SMILES is OC1=C(O)C(O)=C(C=O)C=C1, belongs to isothiazole compound. In a article, author is Capperucci, A, introduce new discover of the category.
The reaction of hexamethyldisilathiane (HMDST) with different carbonyl compounds affords, under the catalysis of CoCl2.6H(2)O or CF3SO3SiMe3 a general access to several thioaldehydes and thioketones including acetylenic derivatives and thioformylsilanes. The use of CF3SO3SiMe3 allows a stereopredetermined entry to both the endo or the exo isomers when cyclohexadiene is used as the trapping agent. Furthermore, when using aromatic and heteroaromatic o-azidoaldehydes, the reactional behavior of HMDST may well be finely tuned to drive the reaction toward the synthesis of o-azidothioaldehydes, fused isothiazole ring systems, aromatic and heteroaromatic o-aminoaldehydes and o-amino thioaldehydes. Finally, taking advantage of the high reactivity of the C-Si bond under fluoride ion catalysis, a selective regiospecific thiophilic functionalization of thioketones, dithioesters, trithiocarbonates and their sulfines by different organosilanes can be obtained.
Related Products of 2144-08-3, Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.I hope my blog about 2144-08-3 is helpful to your research.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com