New research progress on 35285-69-9 in 2021. As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 35285-69-9, Name is Sodium 4-(propoxycarbonyl)phenolate, formurla is C10H11NaO3. In a document, author is Moon, Sanghun, introducing its new discovery. HPLC of Formula: https://www.ambeed.com/products/35285-69-9.html.
A rhodium-catalyzed oxidative annulation of benzimidates with elemental sulfur for the direct construction of isothiazole rings is reported. The proposed reaction mechanism involving Rh(I)/Rh(III) redox is supported by a stoichiometric reaction of metallacycle species as well as DFT calculations. This method is also applicable to selenium cyclization to produce isoselenazole derivatives. The alkoxy substituent at C3 can be used for further functionalization of the azole core.
Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. If you are hungry for even more, make sure to check my other article about 35285-69-9, HPLC of Formula: https://www.ambeed.com/products/35285-69-9.html.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com