Let¡¯s face it, organic chemistry can seem difficult to learn, Recommanded Product: 3′-Nitroacetophenone, Especially from a beginner¡¯s point of view. Like 121-89-1, Name is 3′-Nitroacetophenone, molecular formula is isothiazole, belongs to isothiazole compound. In a document, author is Gruschinski, Sina, introducing its new discovery.
Palladium-mediated Cleavage of S-C Bonds: Preparation and Characterization of Palladium(II) Complexes of 2, 6-Diformyl-4-tert-butylthiophenol Dioxime
The synthesis of air-sensitive 2, 6-diformyl-4-tert-butylthiophenol dioxime H3L3 was achieved by a Pd-mediated SC cleavage of the corresponding S-tert-butyl protected thioether. The novel ligand forms a dinuclear, neutral PdII2 complex, which is stabilized by two N…HO hydrogen bonds to give a pseudo-macrocyclic structure. The crystal structure of a PdII complex of an oxidized isothiazole derivative of H3L3 is also reported.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com