In an article, author is Dalinger, IL, once mentioned the application of 122-59-8, Product Details of 122-59-8, Name is 2-Phenoxyacetic acid, molecular formula is C8H8O3, molecular weight is 152.15, MDL number is MFCD00004296, category is isothiazole. Now introduce a scientific discovery about this category.
Regioselectivity of the substitution for the nitro group in 2,4,6-trinitrobenzonitrile under the action of thiols. The synthesis of 4,6-dinitro derivatives of benzo-annelated sulfur-containing heterocycles
Conditions for the regioselective substitution for a nitro group in the ortho-position in 2,4,6-trinitrobenzonitrile under the action of thiols (PhCH2SH, HSCH2CO2Et or PhSH) in the presence of K2CO3 or KOH were found, and the intramolecular cyclization of the ortho-fragments -SX and -CN (X = Cl or CH2CO2Et) was performed to afford 3-chloro-4,6-dinitrobenzo[d]isothiazole and 3-amino-2-ethoxycarbonyl-4,6-dinitrobenzo[b]thiophene, respectively.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com