Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 18621-17-5, Name is 1-Benzhydrylazetidin-3-ol, SMILES is C3=C(C(N1CC(O)C1)C2=CC=CC=C2)C=CC=C3, in an article , author is Nadirova, Maryana A., once mentioned of 18621-17-5, Application In Synthesis of 1-Benzhydrylazetidin-3-ol.
It was found that the reaction of 5-arylfurfurilamines with maleic anhydride leads to the formation of 6-aryl-3a,6-epoxyisoindole-7-carboxylic acids (the cyclic form), which in solution are in dynamic equilibrium with N-furfurylmaleinamides (the open form). During the esterification of these tautomeric mixtures with methanol in the presence of a catalytic amount of sulfuric acid, methyl esters of 5-aryl-7a-hydroxy-7-methoxy-3-oxo-2,3,3a,4,7,7a-hexahydro-1H-isoindole-4-carboxylic acids, unexpected cleavage products of the 3a,6-oxo bridge of the cyclic form, are formed diastereospecifically. The structure of the obtained products was confirmed by X-ray structural analysis.
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! 18621-17-5, you can contact me at any time and look forward to more communication. Application In Synthesis of 1-Benzhydrylazetidin-3-ol.
Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com