Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Ryan, Sarah J., once mentioned the application of 827-25-8, Name is 2-Bromo-4-chloro-6-nitrophenylamine, molecular formula is C6H4BrClN2O2, molecular weight is 251.47, MDL number is MFCD08275709, category is isothiazole. Now introduce a scientific discovery about this category, Recommanded Product: 2-Bromo-4-chloro-6-nitrophenylamine.
N-Aryl Atropisomerism Induces Facial Selectivity in Benzonitrile Oxide Cycloadditions with Exocyclic Methylene Benzosultams
N-aryl methylene benzo-fused sultams (2,3-dihydrobenzo[d]isothiazole 1,1-dioxides) underwent [3+2] cycloaddition with benzonitrile oxide to give 5-spiro isoxazoline adducts with complete regioselectivity. Steric hindrance by atropisomerism around the N-aryl bond induced facial selectivity in these cycloadditions.
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Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com