Awesome and Easy Science Experiments about 288-16-4

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Reference of 288-16-4, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.288-16-4, Name is Isothiazole, molecular formula is C3H3NS. In a Article£¬once mentioned of 288-16-4

One-step synthesis of 2-alkenecarbodithioate esters from substituted propargyl ethers, and their conversion into isothiazole ring through a [4+1] type oxidative ring closure

Treatment of substituted propargyl methyl ethers with a base and elemental sulfur in the presence of a thiolate ion afforded 2-alkenecarbodithioate esters in good yields. The reaction is assumed to proceed through a pathway involving in situ generation of propadienethione intermediates. Further conversion of 2-alkenecarbodithioate esters into 2,3-dihydroisothiazoles were efficiently performed by treating with chloramine-T through a [4+1] type oxidative ring closure via thiocarbonyl S-tosylimides.

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Reference£º
Isothiazole – Wikipedia,
Isothiazole – ScienceDirect.com