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In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Recommanded Product: 27148-03-4, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 27148-03-4, name is Benzo[d]isothiazole-3(2H)-thione 1,1-dioxide. In an article£¬Which mentioned a new discovery about 27148-03-4

Aurophilic interaction in gold(I) thiosaccharinates: Synthesis, characterization, crystal structures and DFT theoretical study

The reaction of gold with thiosaccharin ligand and additional phosphorous coligands is studied. Four new Au(I) complexes with thiosaccharinate as coordinating counteranion: [Au(tsac)(PPh3)], [Au2(tsac) 2(dppm)]¡¤EtOH, Au2(tsac)2(dppe) ¡¤EtOH, and Au(tsac)(Htsac)2¡¤0.25 EtOH (tsac: thiosaccharinate, C6H4C(S)NSO2-, dppm: bis(diphenylphosphino)methane, dppe: bis(diphenylphosphino)ethane) were synthesized and characterized by means of spectroscopic techniques (IR, UV-Vis, and 1H, 13C and 13P NMR). The crystal structure of two of them, [Au(tsac)(PPh3)] and [Au2(tsac) 2(dppm)]¡¤EtOH, were solved applying single crystal X-ray diffraction and studied using the density functional theory (DFT) formalism. In the latter, the aurophilic interaction between the two gold centers was analyzed and theoretically confirmed.

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Reference£º
Isothiazole – Wikipedia,
Isothiazole – ScienceDirect.com